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81.
An appropriate coupled cohesive law for predicting the mixed mode failure is established by combining normal separation and tangential separation of surfaces in the cohesive zone model(CZM) and the cohesive element method.The Xu-Needleman exponential cohesive law with the fully shear failure mechanism is one of the most popular models.Based on the proposed consistently coupled rule/principle,the Xu-Needleman law with the fully shear failure mechanism is proved to be a non-consistently coupled cohesive la... 相似文献
82.
Observations of sampling are often subject to rounding, but are modeled as though they were unrounded. This paper examines
the impact of rounding errors on parameter estimation with multi-layer ranked set sampling. It shows that the rounding errors
seriously distort the behavior of covariance matrix estimate, and lead to inconsistent estimation. Taking this into account,
we present a new approach to implement the estimation for this model, and further establish the strong consistency and asymptotic
normality of the proposed estimators. Simulation experiments show that our estimates based on rounded multi-layer ranked set
sampling are always more efficient than those based on rounded simple random sampling. 相似文献
83.
Underpotential deposition (UPD) of metals is analysed from the perspective of phenomeno-logical and statistical thermodynamic
considerations; the parameters influencing the UPD shift have been quantitatively indicated using a general formalism. The
manner in which the macroscopic properties pertaining to the depositing ions and solvent dipoles and the nature of the metallic
substrate influence the UPD process are highlighted; earlier correlations of the UPD shift with the work function differences
are rationalised. Anion-induced phase transitions which manifest as sharp peaks in experimental cyclic voltammograms are discussed
using statistical thermodynamic models. 相似文献
84.
Analysis on cohesive crack opening displacement considering the strain softening effect 总被引:4,自引:0,他引:4
In order to investigate the crack propagation in quasi-brittle materials like rock, ceramic and concrete, Hillerborg and his
co-researchers abstracted the fracture process zone in front of a stress free crack in terms of a “fictitious crack zone”.
On the fictitious crack zone, cohesive stresses distribute following a given softening relationship of stress vs. crack opening.
Based on the polynomial or power series expression of cohesive crack opening displacement, the relationship of the cohesive
stress vs. the crack opening displacement is established using elastic theory and integral equation, and some unknown physics
variables are obtained using variation approach. The calculation results gained in this paper are close to the experimentally
test ones. 相似文献
85.
本文针对V循环、W循环和多重网格法中最优光滑次数及循环体个数难以确定的缺点,以Helmholtz方程为例给出自适应的多重网格算法和自适应的完全多重网格算法。 相似文献
86.
A. Stierle C. TiegH. Dosch V. FormosoE. Lundgren J.N. AndersenL. Köhler G. Kresse 《Surface science》2003,529(3):L263
Using high resolution core level spectroscopy, a surface core level shift towards lower binding energy of −0.13 eV is determined for the 2p level of the outwardly relaxed Al surface atoms on NiAl(1 1 0). Density functional theory based calculations with inclusion of final state effects yield a value of −0.14 eV for this shift in excellent agreement with experiment. We show that the initial state approximation yields a value of +0.09 eV, i.e. the inclusion of final state relaxation effects is vital not only to obtain the correct value but even the correct sign for this shift. 相似文献
87.
We present a model of a new paramagnetic defect center which results from the interaction of atomic hydrogen with the MgO(1 0 0) surface. DFT calculations have been performed using periodic supercells and embedded cluster models where long-range polarization effects are included explicitly. The H atom promotes the creation of an oxygen vacancy (F center) by formation of the FS+(OH−) defect where an hydroxyl group is adsorbed near an electron trapped in an oxygen vacancy. This new center has some characteristics similar to those of the classical FS+ centers but a smaller formation energy; furthermore, being globally neutral, it can be treated also with supercell methods. 相似文献
88.
T. G. G. Maffeïs G. T. Owen C. Malag G. Martinelli M. K. Kennedy F. E. Kruis S. P. Wilks 《Surface science》2004,550(1-3):21-25
In this work, we report a scanning tunnelling spectroscopy (STS) study of 30 and 10 nm tin dioxide nanoparticles. The STS spectra give a surface band gap of 2.5 eV for both samples and show that the density of surface states in the band gap is around 6 times higher for the 30 nm particles than for the 10 nm particles. This provides direct experimental evidence for our theoretical model, which predicts a decrease in the surface state density as the particle size decreases, and partly accounts for the improved sensitivity of gas sensing devices fabricated with nanoparticles. 相似文献
89.
《应用数学和力学(英文版)》2005,(3)
IntroductionRecently ,wehaverestudiedtheconventionalconservationlawofenergy ,whichhaswidelybeenusedandisusinginliteraturesofclassicalcontinuummechanicsathomeandabroad ,andpointedoutthatitistheoreticallyincompleteeveninthetraditionalframework .Thepresentsituationoftheconservationlawsofenergyforpolarcontinuaisthesameasthatforclassicalcontinuummechanics.Inordertochangethestatusquo ,itseemstobequitenecessarythatnewprinciplesoftotalworkandenergyshouldbeproposedtotaketheplaceoftheexistingconservatio… 相似文献
90.
Polypropylene (PP)/organo‐montmorillonite (Org‐MMT) nanocomposites toughened with maleated styrene‐ethylene‐butylene‐styrene (SEBS‐g‐MA) were prepared via melt compounding. The structure, mechanical properties, and dynamic mechanical properties of PP/SEBS‐g‐MA blends and their nanocomposites were investigated by X‐ray diffraction (XRD), polarizing optical microscopy (POM), tensile, and impact tests. XRD traces showed that Org‐MMT promoted the formation of β‐phase PP. The degree of crystallinity of PP/SEBS‐g‐MA blends and their nanocomposites were determined from the wide angle X‐ray diffraction via profile fitting method. POM experiments revealed that Org‐MMT particles served as nucleating sites, resulting in a decrease of the spherulite size. The essential work of fracture approach was used to evaluate the tensile fracture toughness of the nanocomposites toughened with elastomer. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 3112–3126, 2005 相似文献